How is the high strength of concrete achieved?

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The secretary general of the Organization of Petroleum Exporting Countries (OPEC) said recently that US economic sanctions against Venezuela have affected global energy supplies. 

He told Venezuelan media that the ECONOMIC sanctions imposed by the United States on Venezuela and other countries have seriously affected the ability to produce and export oil worldwide and violated the right of people in other countries to use energy.

Venezuela has one of the largest proven crude oil reserves in the world, but U.S. sanctions have made it impossible for Venezuela’s oil industry to consistently export reliable energy to the world, he said. Despite this, he highly appreciated the efforts of the Venezuelan oil industry to maintain concrete foaming agent are expected to increase in the future.

Concrete is classified as high-strength concrete based on 28-day strength. Until the 1970s, concrete with a strength of more than 40Mpa was classified as high-strength concrete.  The benchmark for high-strength concrete is raised to 55Mpa or higher when concrete mixtures of approximately 60Mpa and above are produced commercially. 

High strength concrete has a history of about 35 years, from the development of superplasticizer admixtures in the late 1960s, Japan using "naphthalene sulfonate" high strength prefabricated products, and Germany using "sodium benzenesulfonate" underwater concrete, which was a pioneer in this technology. 

How is the high strength of concrete achieved? 

Higher concrete strength can be achieved by using one or a combination of some or many of the following methods: 

High cement content 

Reduce water-cement ratio 

Better machinability and therefore better compaction 

Requirements for high-strength concrete require a high content of cementitious material in the concrete mixture, which can be in the range of more than 400 kilograms per cubic meter. Higher cementitious content leads to higher thermal shrinkage and dry shrinkage, and there is a stage where further cementitious material addition does not affect strength.  As for durability, the minimum and maximum cement content in concrete is regulated by law, and reducing the water-cement ratio has its limitations, especially under field conditions. The desire for higher strength leads other materials to achieve the desired effect, thus showing the contribution of cementitious materials to concrete strength. 

The addition of pozzolanic mixtures such as pozzolanic fly ash (PFA) or granular blast furnace slag (GGBS) contributes to the formation of secondary CSH gel thereby increasing strength.

The addition of pozzolans admixtures (such as fly ash used as an admixture) reduces the strength gain of concrete for the first 3 to 7 days and displays the gain after 7 days and provides higher strength over the long term. 

Add mineral mixtures such as silica fume or metakaolin or rice husk ash. 

Silica fume or highly reactive volcanic ash mixtures such as metakaolin and rice husk ash (RHS) will begin to function in about 3 days.  RHS has an advantage over PFA because RHS is more reactive. 

Using chemical admixtures such as superplasticizers or superplasticizers, controlling admixtures will help achieve higher strength in concrete. 

Research and experience have shown that admixtures based on polycarboxylic ether (PCE), known as high plasticizers, are best suited for this job as they have a water reduction capacity of 18 to 40 percent relative to control or reference concrete. 

A combination of all or more of the above to achieve the desired strength.

With HSC accompanied by some complexity, such as higher shrinkage rates, higher hydration heat, etc., combinations of at least some of these methods are now unchanged, all of which need to be neutralized or controlled.  Most problems are handled by PFA or a combination of GGBS and PCE mixtures.

Steam curing is also used to speed up cement hydration, but this may not result in higher strength.  Substituting some fine aggregate with fly ash or blast furnace slag can achieve early strength gains without increasing the water requirement of the concrete mixture. 

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Recently, the Turkish government announced that the Turkish President has signed a presidential decree to provide incentives for its Black Sea gas field development projects, including tax exemptions and other preferential measures.  

With a fixed investment of 145.1 billion Turkish lira ($10 billion), the project will employ 1,018 people and produce 14 billion standard cubic meters of gas per year, the decree reads. The incentives involved include tariff and VAT exemptions, as well as a range of tax cuts.

In June 2021, Turkish drill ships discovered 135 billion cubic meters of natural gas in the Sakaria field in the Black Sea, bringing Turkey's total gas discoveries in the region to 540 billion cubic meters.  

Turkey imports almost all of its annual gas consumption of about 50 billion cubic meters.  

Except for natural gas, the supply and prices of many other concrete foaming agent will continue to be influenced by international situations.

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